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2 edition of Preparation and properties of coprecipitateds Ni-Mo-Alz 03 hydrodesulphurisation catalysis found in the catalog.

Preparation and properties of coprecipitateds Ni-Mo-Alz 03 hydrodesulphurisation catalysis

Kwan Yoke Ng

Preparation and properties of coprecipitateds Ni-Mo-Alz 03 hydrodesulphurisation catalysis

the preparation of Ni-Mo-Alz 03 catalysts with a range of metal contents and the activity and selectivity of these catalysts for the hydrodesulphurisation of thiophene and related reactions.

by Kwan Yoke Ng

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Published in Bradford .
Written in English


Edition Notes

Ph.D.thesis.Typescript.

SeriesTheses
ID Numbers
Open LibraryOL13977971M

The characterization of the hydrophobic-hydrophilic properties of different types of microporous materials, namely activated carbons, pillared clays and zeolites, was made by the determination of water adsorption isotherms. The data were analysed by the Dubinin and Astakhov (D-A) equation. The use of the E parameter of the D-A equation as a measure of the hydrophobic-hydrophilic character is. Physical properties of the supports and Ni catalysts. Table 1 presents the physical properties of the catalysts used in this study. The specific surface areas of Ni/C, Ni7SBA, and Ni/Al-SBA were , , and m 2 g −1, while the pores volumes were , , and cm 3 g −1, values were lower than those of Pt/C (5 wt%, Sigma-Aldrich), which.

of the most proper methods for catalyst preparation and modification, making a numberofcatalysts,characterizing,andtesting. However,duetotimespanofthis thesis, five catalysts were made and characterized, but only three of them were testedinNynasmicro-reactorwithonefeed. Catalysts preparation and characterization were done at KTH laboratories in. A method for the preparation of chromium-doped (pink), manganese-doped (brown) and cobalt-doped (blue) alumina pigments consisting of spherical particles of broad size distribution .

An Improved and Enantioselective Preparation of the Telaprevir Bicyclic [] Proline Intermediate and Reuse of Unwanted Enantiomer. Lin-Wei Liu, Fei-Ying Wang, Fang Tian, Lin Peng*, and ; Li-Xin Wang*. Bulk Ni-Mo-W hydrodesulfurization catalysts with high catalytic activity were synthesized via direct precipitation and controlled pH precipitation method, respectively. Analysis results shows that the preparation method has great influence on the morphology and pore structure, and further influence the hydrodesulfurization activity. The catalyst synthesized by controlled pH precipitation.


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Preparation and properties of coprecipitateds Ni-Mo-Alz 03 hydrodesulphurisation catalysis by Kwan Yoke Ng Download PDF EPUB FB2

In this study, a series of cobalt–molybdenum–phosphorous acid (Co–Mo–P) impregnating solutions with various Co/Mo molar ratios (, ) were synthesized, and desulfurization catalysts were prepared by mixing the solutions with γ-Al2O3 through an incipient-wetness impregnation method.

The Co–Mo–P supported γ-Al2O3 catalysts were tested in the hydrodesulfurization of Cited by: 1. A series of Al 2 O 3 –ZrO 2 composite supported NiMo catalysts with various ZrO 2 contents were prepared.

Several techniques including XRD, SEM, N 2 physisorption, H 2-TPR, and UV–vis DRS were used for typical physico-chemical properties characterization of the ZrO 2 –Al 2 O 3 composite supports and their NiMo/ZrO 2 –Al 2 O 3 catalysts.

The test results showed that the Cited by: CO-Mo/Al2O3 commercial catalytic used wetness impregnation method to prepare Co-Mo B/Al2O3 and Co-Mo P/Al2O3. We study the characterization of this catalyst which contains wt. Fig. 1 shows the catalytic performance of the prepared catalysts.

Compared with the benchmark Co/ZrO 2 catalyst, the dicarboxylic acid addition in the impregnation solution improved the activity of Co/ZrO 2 catalysts. The CO 2 conversion was raised from 38% to 65% and the CH 4 selectivity stayed at 99% with little change with time over the Co/ZrO 2 catalysts.

The increased Cited by:   To determine the effect of preparation methods on the state of Zr, two catalysts IE-Ni 2 Al Zr W and CP-Ni 2 Al Zr W were characterized by XPS.

The spectra of Zr 3d are shown in Fig. 7, which can be deconvolved into two peaks: Zr 3d 3/2 of Zr 4+ around eV and Zr 3d 5/2 of Zr 4+ around eV [33].Cited by: 4.

MoP/MCM was prepared from its oxidic precursors by sulfidation at °C for 3 h using 10% H 2 S/H 2, followed by temperature-programed reduction in H resulting catalyst, MoP/MCM(SR), showed considerably a higher catalytic activity in the hydrodesulfurization (HDS) of dibenzothiophene (DBT) and 4,6-dimethyldibenzothiophene (4,6-DMDBT) than a catalyst prepared by.

1. Introduction. Innovation in the development of Co–Mo–Al 2 O 3 and Ni–Mo–Al 2 O 3 catalysts has been driven by the need to produce clean fuels, based on the pressing requirement for environmental protection.

Extensive studies on these hydrotreating (HDT) catalysts revealed that a high dispersion of MoS 2 nanocrystallites on alumina and a precise location of Co or Ni promotor atoms on.

Hydrodesulfurization Hydrodesulfurization (HDS) or Hydrotreating is a catalytic chemical process widely used to remove sulfur compounds from refined petroleum products such as gasoline or petrol, jet fuel, diesel fuel, and fuel oils. One purpose for removing the sulfur is to reduce.

that are distributed on a base and main catalysts are those of cobalt–molybdenum and nickel–molybdenum supported on alumina that both of them can remove sulfur components [2]. Alumina has outstanding textural and mechanical properties and. A novel method for preparing Ni 2 P/C-x (x = preparation temperature, °C) catalysts in a flowing N 2 atmosphere by decomposition of hypophosphites was proposed, and the effect of preparation temperature on the hydrodeoxygenation performance of the catalysts was further investigated.

X-ray diffraction (XRD), N 2-adsorption specific surface area measurements, CO uptake, and X-ray. Kinetics experiments have determined the reaction network in the hydrodesulfurization of dibenzothiophene catalyzed by sulfided CoO‐MoO 3 /γ‐Al 2 O 3 at °K and atm. The predominant reaction is a direct sulfur extrusion, giving biphenyl and hydrogen sulfide; the biphenyl is subsequently hydrogenated slowly to give cyclohexylbenzene and then bicyclohexyl.

Hydrodeoxygenation of anisole as bio-oil model compound over supported Ni and Co catalysts: Effect of metal and support properties. Catalysis Today, DOI: / The Mo-Ni 2 P/SBA catalysts with 1% (w, mass fraction) Mo loading exhibited the highest HDS activity. The conversion of the DBT reached %under reaction conditions of ℃ and MPa.

The HDS of DBT proceeded mainly via the direct desulfurization (DDS) pathway over all of the tested Mo-Ni 2 P/SBA catalysts.

Sulfur compounds in fuel oils are a major source of atmospheric pollution. This study is focused on the hydrodesulfurization (HDS) of dibenzothiophene (DBT) via the coupled application of wt% Pd-loaded Co–Mo/Al 2 O 3 and Ni–Mo/Al 2 O 3 catalysts with ionic liquids (ILs) at ambient temperature ( °C) and pressure (1 MPa H 2).The enhanced HDS activity of the solid catalysts coupled.

the SBA pore system. The preparation, characteri-zation and discussion of hydrodesulphurization activi-ties and its relation to physico-chemical properties of supported phase form the contents of this study. Experimental Preparation, characterization and activity of catalysts SBA was prepared by following the reported proce.

direct preparation of co-mo-p impregnating solutions for the preparation of hydrodesulfurization catalysts Article (PDF Available) in Phosphorus Research Bulletin January with. Textural properties All the results of the textural properties of the Na-M41 support and the various catalysts prepared using different reduction temperatures are listed in Table general, the BET surface areas of the Na doped support M ( m 2 g −1) were lower than that of bare support ( m 2 g −1), a similar trend was observed with the pore volumes and the average pore.

Co-promoted MoS2 catalysts for hydrodesulfurization (HDS) were prepared from a new amorphous MoS2 precursor and tris-(N,N-dimethyldithiocarbamato)-cobalt(III) as promoter source. Basic mixed oxides MgAl, ZnMgAl, and ZnAl were successfully prepared from hydrotalcite precursors synthesized by urea method.

Materials with the same molar ratio (M2+/Al3+) = 2 were studied to describe the influence of Mg/Zn ratio on their physicochemical properties. Materials were tested as catalysts of the aldol condensation of furfural with acetone.

It is revealed that new strong acid sites ( > H 0 > ) were generated after the first 2 h of ion exchange and that the following ion exchanges had little effect on the acidic properties. XRD patterns of the mesoporous materials indicate that the structure of siliceous MCM was improved by HNO 3 ion exchange.

2. HYDROTREATING CATALYSTS Catalysts developed for hydro-treating include tungsten and molybdenum sulfides on alumina. These metals are considered the hydrogenating catalysts but their properties are modified by adding either cobalt or nickel sulfides. Nickel sulfide, nickel thio-molybdate.A short review of recent advances in CO2 hydrogenation to hydrocarbons over heterogeneous catalysts Wenhui Li,a Haozhi Wang,a Xiao Jiang,c Jie Zhu,a Zhongmin Liu,b Xinwen Guo *a and Chunshan Song*ac CO 2 hydrogenation to hydrocarbons is a promising way of making waste to wealth and energy storage, which also solves the environmental and energy issues caused by CO.Dehydroepiandrosterone (DHEA, 2) is an important endogenous steroid hormone in mammals used in the treatment of a variety of dysfunctions in female and male health,1 as well as an intermediate in the synthesis of steroidal drugs, such as abiraterone acetate which is used for the treatment of prostate cancer.2−4 In this manuscript we describe a novel, concise, and cost-efficient route toward.